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Zinedine Zidane said this year will be even "more difficult" as Real Madrid begin their defence of the La Liga title on Sunday evening at Deportivo.
Valencia have signed defender Jeison Murillo from Inter Milan, the club confirmed on Friday.
Simone Zaza was the match-winner as Valencia started their La Liga campaign with a 1-0 home victory over 10-man Las Palmas.
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The back of Barcelona's shirts will feature the city rather than players' names for Sunday's game in homage to the victims of Thursday's attack.
Luis Suarez will be out of action for "at least four to five weeks" after suffering a knee injury late in Barcelona's loss to Real Madrid.