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They fell behind after one minute but, after that and inspired by their Brazilian star, PSG turned on the style to cruise past the Scottish champions.
Matteo Darmian and Daley Blind were exposed by Basel, who took advantage of the full-backs en route to a late 1-0 win over Manchester United.
Relive the best moments from Wednesday's Champions League matches, highlighted by PSG's 7-goal performance over Celtic.
Jose Mourinho says Manchester United were made to pay for not capitalising on a "perfect" first-half performance in a 1-0 loss to Basel.
With their perfect starts still intact, the FC crew debate whether PSG or Manchester City are the better team in Europe.
Basel were by far the better side in the second half and their work was rewarded with a goal in the 89th minute.