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Louis Moult sent Motherwell to the League Cup final as Rangers boss Pedro Caixinha and opposite number Stephen Robinson were sent to the stand.
A second-half double by substitute Moussa Dembele gave Celtic a 4-2 win over Hibernian and booked the Hoops' place in the Scottish League Cup final.
Celtic eased into the Betfred Cup semi-finals with a dominant 4-0 win over Dundee at Dens Park.
Extra-time strikes from Daniel Candeias and Eduardo Herrera fired Rangers into the Betfred Cup semi-finals as they battled to a 3-1 win over Partick.